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All You Need to Know About Anti-Reflective Lenses

By Larry Clarke

Issue Date: February 2004
Expiration Date: February 28, 2007
This course is approved for one (1) hour of continuing education credit by the
American Board of Opticianry (ABO). Course # SWJP217-1
Learning Objectives:
Upon completion of this program, the participant should be able to:
  1. Communicate to patients and customers the importance of AR lenses.
  2. Demonstrate the typical AR application process.
  3. Explain why refractive index is a key factor in defining the need for AR.
 


HOW DOES AR COATING WORK?

The basic concept for how anti-reflective coatings work is the optical interference model. Each coating layer in the AR stack combines with previous layers to cancel out a broad range of light waves by introducing opposite, or destructive, waves that are out of phase. Thus, reflective properties of that range of light are neutralized. By applying the principle of optical interference, we are able to increase light transmission to nearly 99 percent in most cases. The result is a reduction of reflections over a broad range of wavelengths... and clear, crisp vision for your patients.

DESTRUCTIVE INTERFERENCE MODEL

By causing the reflection from the second surface to be exactly 1/2 wave length out of phase from the reflection from the first surface, an AR coating causes the two reflections to cancel each other out, eliminating reflection. Please note that in the interest of simplicity, the destructive interference model used is based on a single wave length of light entering a lens at normal incident. In the case of a real lens coating, the mathematical formula and models used to design an AR coating are much more complex. (See illustration on following page.)

STANDARD LENS WITHOUT AR

Standard, uncoated lenses can decrease light transmission by up to 15 percent of available light. This is caused by visible reflections on the front and back surface of the lens, as well as internal reflections. The higher refractive index of a lens material equates to the greater incidence of reflections and glare. (See illustration on following page.)

WHY DO SOME AR BRANDS REFLECT A DIFFERENT COLOR THAN OTHERS?

When seen from an angle, all AR lenses reflect a small amount of color/hue, typically referred to as residual color. Some AR brands look green, while others appear blue or yellow-green. This is a natural phenomenon associated with the reflectance curve of a broadband AR coating across the visible spectrum of light. AR coatings have a peak reflectance (approximately 1 percent) at some point on the visible light spectrum and it is the color associated with that peak, which is reflected more than other colors.

Most AR producers choose their AR layer design and resulting peak color reflection based on customer preference or visual performance goals. The ability to help control manufacturing consistency is also a major factor. Peak reflectance tends to drift slightly from day to day, affected by environmental changes in production such as vacuum chamber cleanliness or even changes in humidity. Many AR coatings tend to have peak reflectance in the 520 to 550nm range of the light spectrum, the green area of visible light that also tends to be the easiest color to produce consistently. Some manufacturers move the curve peak closer to the blue end of the spectrum, while others move the peak toward the yellow.

Visual performance such as eye sensitivity during daytime or twilight has also been cited as criteria for residual color choice. It is, however, difficult to find credible evidence or studies on this subject that will make the choice an obvious one. Feel free to ask your supplier how they chose their peak reflectance color.

IS IT POSSIBLE TO HAVE A COMPLETELY CLEAR AR?

Theoretically, yes it is possible... but this requires a very complicated and tricky AR stack design that is nearly impossible to consistently maintain in a real production environment. In addition, some companies that attempted to market a near-clear or flesh-toned AR experienced resistance. Upon receiving their new eyewear, consumers sometimes expressed buyer's remorse when they were not able to easily recognize a visual difference from a normal clear lens.

AR Coated Lens

Destructive Interference Model
By causing the reflection from the second surface to be exactly 1/2 wave length out of phase from the reflection from the first surface, an AR coating causes the two reflections to cancel each other out, eliminating reflection.

SHOULD THE REFRACTIVE INDEX OF AR MATCH THE REFRACTIVE INDEX OF THE ACCOMPANYING LENS MATERIAL?

Light Transmission= Clear, Crisp Vision
Lens Material
Index
Without AR
Including Multi-Layer AR

CR-39

1.50
92.06
99.1
Glass
1.52
91.04
99.2
Polycarbonate
1.59
89.4
99.2
High-Index Plastic
1.60
89.4
99.0
Super High-Index Plastic
1.67
87.8
98.2
Recently a number of AR manufacturers advertised that they have matched the refractive index of their AR to that of a particular high- index lens material. The question arises, does this combination create a benefit? According to the science of thin film design, AR coating should match the refractive index of the hardcoat, not the lens material. The question then becomes: when the indices of AR and hardcoat match, is there a benefit? The answer to this question is still not simple. For instance, if the AR and hardcoat refractive indices match, but the hardcoat and lens material indices are not in harmony, any benefit derived from the AR/hardcoat match would immediately be offset. Whenever there is a mismatch between the refractive index of lens material and hardcoat, the result is what is traditionally referred to as birefringence, the rainbow effect often seen when a lens is viewed from the side. AR coatings will never hide this effect. Having said all this, it is important to note that a slight advantage does exist when the refractive index of all three components is in harmony--lens material, hardcoat and AR coating.

Normal CR-39 Lens

Standard Lens Without AR
Standard, uncoated lenses can decrease light transmission by up to 15% of available light. This is caused by visible reflections on the front and back surface of the lens, as well as internal reflections. The higher the refractive index of lens material, the greater incidence of reflections and glare.

In reality, most hardcoats have a refractive index of approximately 1.5; the highest index for a hardcoat currently used in our industry is 1.65. A common practice among AR producers is to batch lenses from numerous manufacturers with varying inherent hardcoat indices in the same coating run. This forces the AR coater to choose an AR index that matches most hardcoats, typically around 1.5. In a perfect world, AR producers would have the ability to coat all "like" lenses in each batch, where the indices of the lens material and hardcoat are a perfect match. Other than product produced by lens manufacturers (commonly referred to as stock lenses), there are very few AR producers who generate enough volume to justify this degree of segregation. And even though there are some minor cosmetic and visual advantages to a total index matching system, the question is whether or not the typical consumer can see the difference; and if so, is it of value to them? Consumers to the ophthalmic industry tend to place greater value on attributes such as durability and lens thickness, as compared to other lens features.

THE NEED FOR AR

Refractive index of a lens material is a key factor in defining the need for AR. As evidenced by the following table, the higher the index of a lens, the more reflective it is; therefore, to achieve maximum light transmission and resulting wearer comfort, it is easy to see that AR benefits all lens products but becomes even more critical on high-index lenses.

HOW IS AR APPLIED?

The anti-reflective process takes place in a specially designed coating lab, through a series of steps taking anywhere from four to 10 hours. A truly effective AR process incorporates the entire laboratory--from surfacing to coating to finishing. It must begin in the most pristine of conditions to be successful. The environment must be clean and dust-free with a positive air-flow. After lenses are cleaned, they are placed inside of a vacuum chamber and microscopically thin layers of low, medium and high-index materials are alternately applied in succession to both the front and back lens surfaces. Computer technology controls the process with extreme precision so that each layer is accurately applied. The following six steps demonstrate a typical AR application process. To better understand the precision with which this process must take place, let's put it into perspective: the thickness of an AR coating is equivalent to 1/5,000th width of a human hair.

 

1 - Hardcoating After casting or surfacing, an important step is for all lenses to receive a scratch-resistant hardcoat prior to AR coating. The hardcoat can be applied using a thermally cured dipcoating system or via a process as simple as UV-cured spincoating.

2 - Hand Cleaning Lenses are individually hand cleaned to remove any remaining ink markings, dirt and debris.

3 - Ultrasonic Cleaning Lenses travel robotically through a cleansing process, alternating between tanks of detergent, tap water and deionized water.

4 - Degassing Lenses are baked in a degas oven to remove all internal moisture and provide optimal conditions for successful AR coating application. The lens substrate determines oven temperatures, varying from 50C to 75C, as well as processing time, varying accordingly from one to four hours.

5 - Inspection Hand inspection assures optimal surface preparation prior to the AR process.

6 - Vacuum Coating Lenses are loaded into a rotating dome and various low, medium and high-index inorganic chemicals are loaded into the electron beam gun. The chamber is sealed and vacuum pumps establish the prescribed vacuum pressure. Various low, medium and high-index chemical layers are evaporated from the electron beam gun at approximately 2000C and are deposited, one layer at a time, until the AR stack is complete. Finally, the hydrophobic top-coating is applied. The total process takes approximately 90 minutes. Lenses are then removed, inspected and forwarded to the lab finishing department.

WHY DO AR LENSES GET DIRTIER THAN NORMAL LENSES?

They don't. With normal lenses, reflections tend to hide the dirt whereas with AR lenses, because they are so much clearer, it is easier to see the dirt. It is like an early detection system. A patient with normal lenses will typically walk around for a day or more at a time with dirty glasses that affect their sight due to diminished transmission or light dispersion caused by dirt that they don't notice. With AR lenses, the dirt is noticeable and causes the patient to clean their lenses more often resulting in better and safer vision. And, although the earlier generations of AR lenses were difficult to clean, the newest generations are far easier to care for than ever before.

WHAT IS THE BEST WAY TO CARE FOR AR LENSES?

Recommend a regular lens cleaning regimen, complete with easy-to-use AR specific products that fit the active lifestyles of your patients. Ask your AR provider about what lens cleaning products they currently have available:

  • Lens spray cleaner, specially designed for anti-reflective lenses
  • Microfiber lens cleaning cloth
  • Pre-moistened, disposable lens cleaning cloths... great for travel and everyday use

Be careful about recommending household cleaners. When instructed by a dispenser to use a certain brand of household dishwashing soap, some patients interpret this to mean "any household soap." Unfortunately, some caustic soaps contain ammonia, which will harm AR. Patients will typically experience the best results when using cleaners specifically designed for AR lenses.

ADVANCEMENTS IN HYDROPHOBIC TOPCOATING

Hydrophobic topcoating is a thin, organic, polymer seal applied as the final layer of an AR coating stack. Numerous new polymers have been introduced during the past several years that substantially increase the chemical resistance, repellency, abrasion-resistance and ease of cleaning. The end result is an added patient benefit as most AR coatings produced today are as easy to clean as normal lenses.

WHY ARE TODAY'S AR LENSES BETTER?

During the past 10 years, most issues associated with AR adhesion have been solved and AR developers have turned their attention toward increasing abrasion resistance. Numerous new brands have been introduced during the past three years that boast of two- to three-fold increases in scratch-resistance. Increased hardness is achieved through the application of specially designed hardcoat prior to AR coating with a traditional AR stack or through the introduction of new generation harder AR stacks on top of traditional hardcoat. All of these new methods and brands result in superior quality AR and are contributing to the increased growth rate of anti-reflective lenses.

QUALITY CONTROL AND UNDERSTANDING PLASTICS

Ten years ago, most hardcoats were designed strictly for hardness or tintability and AR compatibility was not considered. Fortunately, this has changed dramatically and most hardcoats, especially UV cured backside spin coatings, are now being developed with AR compatibility as the overriding performance criteria. In addition, most AR coatings 10 years ago were applied by custom coating houses that had nothing to do with the manufacturing or surfacing of a lens. In many cases, custom coating houses had no control over the lens or hardcoat brands sent to them, nor in the surfacing practices used on the lenses prior to AR coating. Without knowledge of these factors, custom coating facilities faced a situation where they had to treat all lenses the same and therefore had to compromise quality practices. Today, on the other hand, most AR coatings are applied in or next to the same lab that manufactured and/or surfaced the lenses; this adds a great amount of control over the ultimate quality an AR lab can achieve. Labs can choose the best hardcoat brands and can also optimize their surfacing practices, back-side coating practices and actual AR process to achieve the best quality final product.

Dispensing Tips

START IN THE EXAM ROOM
Patients put a lot of value on their doctor's advice, so why not steer them toward something that will give them an additional visual and cosmetic benefit? When describing your patient's new prescriptions and associated lens recommendations, remember to recommend AR lenses and tell your patient why.

WEAR AR YOURSELF
Everyone on staff who wears eyewear should wear AR lenses. How will your patients have faith in the product if their own optician or doctor doesn't wear it? Personal testimonials about why a staff member loves wearing AR lenses can carry a lot of weight.

DISPLAY AND DEMONSTRATE
Patients can feel bogged down and confused by a lot of technical explanations, especially if they are also hearing about new lens materials and designs. A display showing an uncoated and an AR-coated lens side-by-side is a simple, effective explanation. Ask the patient, "Would you rather your lenses look like this or like this?" Many lens manufacturers, coaters and laboratories supply comparison displays to their customers.

STAFF EDUCATION
A well-informed staff is an effective, helpful staff. Excellent training tools are available from many manufacturers to keep your staff well-versed on the subject. Hold role-playing exercises in which staffers educate "patients" on the benefits of AR lenses.

WHO BENEFITS FROM AR LENSES
Every patient can benefit from more light to the eye. And every patient should be given that opportunity. Remember to discuss:

FUNCTIONAL BENEFITS
Night drivers
Computer users
Sunglass wearers
Sports participants
People who work in visually demanding occupations such as police officers,
   firefighters and pilots

COSMETIC BENEFITS
People see you, not your lenses
Attention focuses on your eyes, not the distracting glare
AR on photochromic lenses makes them look clearer indoors and eliminates
   the glare that can occur in the darkened state



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